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24 Hr Emergency Response

800-377-3648

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6,000 Environmental Remediations Since 1975

Remtech © 2017


Location:  Minneapolis, Minnesota

Client:  Major Transportation Company

Contract Amount: $30,000


PROBLEM


Three 28-foot trailers on a three-car articulated rail flatcar were destroyed by fire. The State Fire Marshal indicated that the most probable cause of the fire was a load shift on a LTL and autoignition of chemicals. The LTL was being held responsible for a loss of $300,000 by an LTL carrier on an adjacent flatcar.


SOLUTION


Remtech engineers was engaged (four months after the incident) to conduct an independent fire investigation. The chemicals involved were dilute janitorial and metal cleaning products and oil based paints. Dental cleaning materials contained 15% sulfamic acid and 10% sodium hydroxide solutions. An aluminum cleaner contained 10 to 30% phosphoric acid.


Paints contained solvents, powdered metals (aluminum, titanium), and propellants. Other potential metal catalysts included the aluminum trailer, copper, brass, aluminum and zinc electrical fittings. Potential combustible reactants included paper, cardboard, and cloth medical dressings.


Janitorial cleaning chemicals contained glycols, surfactants, and ammonia compounds.


Articulated Rail Flatcar Fire
Burn Residues Following the Fire

Articulated Rail Flatcar Fire

Burn Residues Following the Fire

Samples of chemicals involved in the fire were obtained from product manufacturers. Potential reaction consequences were determined using A Method for Determining the Compatibility of Hazardous Wastes. Reactions with the greatest potential to produce heat or fire were selected for testing. Potential binary, tertiary, and synergistic heat of reaction tests were conducted.  


Induction reaction periods were determined to ensure that adequate reaction times were employed.  The order or sequence of chemical reactants was also varied to determine maximum heat generation.  Initial tests were conducted in one liter glass reactors with a digital thermocouple equipped with an immersion probe.  Reactions yielding the highest reaction temperatures were scaled up (8 liter glass reactors) to determine if heats of reaction were mass limiting.  Results indicated that insufficient heats of reaction were produced to elevate temperatures above threshold autoignition temperatures (for wood and cardboard 400 to 500 oF).


The cause of the fire was determined not to be due to the autoignition of chemicals on the trailer.  The most probable cause of the fire was the crushing of pressurized paint spay cans during a load shift and the release of propellants and ignition by an open flame such as sparks from railcar wheels.  


A video tape of typical flatcar braking and spark generation was provided to Remtech for determination of spark temperature and projection distances.  Still frame capture indicated that molten sparks released during braking had sufficient mass and projection to enter the nose of the trailer where propellants could be ignited.


COSTS/BENEFITS


Remtech's investigation and accident reconstruction shifted the responsibility of the fire cause away from the LTL and saved them an estimated $300,000.


Rail Flatcar Chemical Fire Investigation

Web Inquiries: 770-427-7766 Extension 4

Fax: 770-427-7001

Email: webmaster@remtech-eng.com

Copyright Remtech Engineers, 2017

Remtech EngineersTM

200 Cobb Parkway North

Suite 208

Marietta, Georgia 30062

Phone: 770-427-7766 or 800-377-3648

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